well to start with Visual Basic, you can read or download a few books.
i like 2 books :
1.Mastering Microsoft Visual Basic 2008(or 2010 if you have VS2010) by Evangelos Petroutsos.
and
2.Pro VB 2008 and the .NET 3.5 by Andrew Troelsen.
you can also download the ebooks.
In addition to the link given by JFergulbops you can also go through this link :
http://www.java2s.com/Code/VB/CatalogVB.htm
then hook on to some good ASP.NET book and start programming!!
Good Luck! :thumbsup: