Try to make your Web method at Default.aspx.cs rather than in different asmx file and remove
ServicePath="AutoComplete.asmx"
From your code
at CS page
[System.web.Webservices.WebMethod]
public string[] GetCountriesList(string prefixText)
{
DataSet dtst = new DataSet();
SqlConnection sqlCon = new SqlConnection(ConfigurationManager.AppSettings["ConnectionString"]);
string strSql = "SELECT CountryName FROM Tbl_Countries WHERE CountryName LIKE '" + prefixText + "%' ";
SqlCommand sqlComd = new SqlCommand(strSql, sqlCon);
sqlCon.Open();
SqlDataAdapter sqlAdpt = new SqlDataAdapter();
sqlAdpt.SelectCommand = sqlComd;
sqlAdpt.Fill(dtst);
string[] cntName = new string[dtst.Tables[0].Rows.Count];
int i = 0;
try
{
foreach (DataRow rdr in dtst.Tables[0].Rows)
{
cntName.SetValue(rdr["CountryName"].ToString(), i);
i++;
}
}
catch { }
finally
{
sqlCon.Close();
}
return cntName;
}
I Hope It will work