converting a listview selected item to string

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VB

To start off im new to VB and I m trying to create an application launcher that pulls the items i want to launch from a folder.I can get the items to load with the icon, the only are im having is turning the selected item in a list view box to string so i can use it a a variable in the rest of my code.

here is the code i have so far, Help would be great. my main goal is to make it so when i double click an item it will open what ever that item is. ie a vbs script or a text file.

Imports System.IO

Public Class Form1

    Private Sub Form1_Load(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles MyBase.Load
        Dim Dir As New DirectoryInfo("C:\Program Files (x86)\AutoHotkey")
        FillListView(Dir)
    End Sub

    Private Sub FillListView(ByVal Folder As DirectoryInfo)
        Static ImageList As New ImageList With {.ColorDepth = ColorDepth.Depth32Bit, .ImageSize = New Size(22, 22)}
        Static ImgIndex As Integer = 0

        ListView1.LargeImageList = ImageList
        ListView1.View = View.Tile

        For Each F As FileInfo In Folder.GetFiles("*.exe")
            ImageList.Images.Add(Drawing.Icon.ExtractAssociatedIcon(F.FullName))
            ListView1.Items.Add(F.Name, ImgIndex).Tag = F
            ImgIndex += 1
        Next

        For Each F As FileInfo In Folder.GetFiles("*.txt")
            ImageList.Images.Add(Drawing.Icon.ExtractAssociatedIcon(F.FullName))
            ListView1.Items.Add(F.Name, ImgIndex).Tag = F
            ImgIndex += 1
        Next

        For Each F As FileInfo In Folder.GetFiles("*.hta")
            ImageList.Images.Add(Drawing.Icon.ExtractAssociatedIcon(F.FullName))
            ListView1.Items.Add(F.Name, ImgIndex).Tag = F
            ImgIndex += 1
        Next

        For Each F As FileInfo In Folder.GetFiles("*.vbs")
            ImageList.Images.Add(Drawing.Icon.ExtractAssociatedIcon(F.FullName))
            ListView1.Items.Add(F.Name, ImgIndex).Tag = F
            ImgIndex += 1
        Next

        For Each Dir As DirectoryInfo In Folder.GetDirectories
            FillListView(Dir)
        Next
    End Sub


End Class